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By keeping an eye on syndicated reviews, children s furniture seller The Land of Nod discovered how to make product improvements. One of their products was a play/activity table for kids. It scored 4.8 out of 5 stars. People liked it a lot and 90 percent gave it that all-powerful would recommend it to a friend accolade. But a closer review of the reviews revealed that customers felt the surface of the table was too prone to scratching. The product designers discovered a harder type of wood that was more scratch-resistant and offered a new version of the table. The marketing team reached out to those who had mentioned this product inadequacy; they offered a replacement to those who had spoken out. Customer service became great customer service, happy customers became advocates, and everybody who buys from The Land of Nod knows they are dealing with a company that knows how to listen. Random reviews are valuable for product development (they tell you what they want) and for product marketing (they tell you what resonates). It can also be the best promotional material ever. When your customers tell the world that your product rocks, it s the best possible advertisement and some would say the single most important metric ever. You always hope to overhear: Oh, I ve been using Brand X for years and it s the best thing since sliced bread even better! That s more than a mention. It s more than a compliment. It s more than a willingness to wear your T-shirt or sport your logo on their backpack. It s somebody putting their personal reputation on the line by telling others that

Self-assembly generally refers to a process in which components, either separate or linked, spontaneously form order aggregates (Whitesides and Boncheva, 2002; Whitesides and Grzybowski, 2002) Self-assembly has been extensively explored to develop a variety of well-de ned structures through bottom-up approaches (Forster and Plantenberg, 2002; Philp and Stoddart, 1996) Azo polymers with specially designed functional groups or chain structures can undergo different types of selfassembly Multilayer thin lms composed of azo polyelectrolytes have been obtained through sequential electrostatic layer-by-layer self-assembly (Laschewsky et al, 1997; Lvov et al, 1997; Wang et al, 1997a) The azo chromophores in the.

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lms can automatically possess the noncentral symmetric alignment, and the thin lms can show the signi cant second-order nonlinear optical (NLO) effect without electric eld poling The electrostatic layer-by-layer lms containing azo chromophores can also show photoresponsive behavior related with the photoisomerization (Wu et al, 2001; Dante et al, 1999) The block copolymer containing mesogenic azobenzene units in one of the blocks has been developed (Morikawa et al, 2006) The polymer can form thin lms with well-organized cylinder structures and photoinduced alignment properties Amphiphilic azo block copolymers have been prepared by ATRP, and light-responsive micellar aggregates have been obtained (Wang et al, 2004) Other recent progresses in the self-assembly of azo polymers can be seen in other chapters of this book This chapter reviews some recent research progresses concerning the colloidal spheres constructed from the polydispersed amphiphilic azo polymers.

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In contrast to the amphiphilic block copolymers being reviewed in s 6 and 7, the polymers discussed in this chapter are polydispersed amphiphilic azo homopolymers and random copolymers The polymers can be prepared through some relatively simple methods and are easily available from many resources The polymers can form uniform colloid spheres in selective solvent through selfassembling process The colloidal spheres can form ordered two-dimensional (2-D) arrays through vertical deposition, and the 2-D arrays can transform to ordered porous lms through in situ structure inversion In certain sense, these processes can well disclose the essence of self-assembly in which not only components spontaneously form order aggregates but also order can be produced from disorder Such self-assembled structures can be expected to show photoresponsive properties related to both the azo chromophores and the architectures at and beyond molecular level.

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