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The rst and simplest technique for depositing a target material on a backing foil is by evaporation of a solution of the desired material on the foil Generally, this is a poor choice as the solute tends to deposit at the edges of the dried droplet, leading to variations of up to a factor of 100 in thickness over the area of the deposit Uniformity can be improved by using a spreading agent such as insulin to coat the surface of the backing material prior to evaporation A method that was widely used in the past is electrospraying A solution of the nuclide to be deposited is prepared in a volatile, nonconducting liquid like acetone, alcohol, and the like A capillary is drawn out to a ne point such that no liquid can escape under normal conditions and lled with the solution.

n LiveCD Project The LiveCD project (http://livecd.berlios.de) is an initiative aimed specifically at creating a live CD from a Linux distribution. Because the tools currently work only on Mandrakelinux and PCLinuxOS, this project is probably a good place to start if you want to produce a live CD that is compatible with either of those distributions. There are currently more than a dozen live CD distributions that have been created from the LiveCD project. Of the projects I ve just mentioned, I d recommend starting with a KNOPPIX or Damn Small Linux distribution for your first attempt at remastering. Because there are a lot of people using those, or other distributions based on Debian/KNOPPIX technology, there are mature procedures and forums to help you get over any bumps in the road.

A ne wire is threaded though the capillary to within a few millimeters of the tip A high voltage (3 10 kV) is applied between the wire in the tube and the backing material on which the deposit is to be made One gets a spray of charged drops that are collected on the backing material, placed 1 cm from the capillary The volatile solvent evaporates leaving a uniform lm The deposit can be calcined..

NULLCMD path PATH POSTEDIT PROMPT PROMPT2 PROMPT3 PROMTP4 prompt PS1 PS2 PS3 PS4 psvar PSVAR RANDOM READNULLCMD REPORTTIME reply REPLY RPROMPT RPS1 RPROMPT2 RPS2 SAVEHIST

You must supply a numeric variable for all the selections except Count, which can be any data type.

illustrates the point that chemical equilibrium is shifted when a radioisotope is substituted for another isotope. (Note that when X X*, K 1). Table 4.2 also shows the important fact that the greater the mass difference between isotopes, the larger the equilibrium isotope effects are. In general, it has been found that such effects can be neglected when the atomic number is greater than 10. Kinetic isotope effects are very important in the study of chemical reaction mechanisms. The substitution of a labeled atom for an unlabeled one in a molecule will cause a change in reaction rate for Z , 10, and this change can be used to deduce the reaction mechanism. The change in reaction rate due to changes in the masses of the reacting species is due to differences in vibrational frequency along the reaction coordinate in the transition state or activated complex. Experimentally, it is relatively straightforward to measure the existence and magnitude of kinetic isotope effects. Consider the reaction shown below, proceeding through a reaction intermediate, AB, as A B AB products ! ! Let S0 and Sg be the speci c activities of B at time t 0 and after a fraction g of the reaction has been completed, respectively. If B is the only labeled reactant, we have d B k A a B b dt And assuming B is present as a tracer d B* k A a B* B b 1 dt (4:11) (4:10)

The redirection is all done by links. Check the man page for link by typing man link in the Terminal window. Links are like aliases, except that links are tailored to work transparently with command-line tools and shells scripts.

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